If system says “unable to load QT5Qml.dll” it normally means that some depended library is missing. Hence I am assuming that your deployment to the target is not correct. Please also be aware that you might need the c++ runtime for the platform to copy. You can use the tool called dependency walker for the desktop to find out dependencies even for WEC2013. Also its recommended to use the windeployqt, you can find the documentation on deployment here.
For the MFC part its most likely also a dependency issue but also not the quite common case to load Qt in a MFC application, hence normally just done for migration projects or a mixed application, but which is more complicated.